由M3N@C80合成苯基-C81-丁酸甲酯（PCBMs）及其结构

Syntheses and structures of phenyl-C81-butyric acid methyl esters (PCBMs) from M3N@C80.

作者信息

Shu Chunying, Xu Wei, Slebodnick Carla, Champion Hunter, Fu Wujun, Reid Jonathan E, Azurmendi Hugo, Wang Chunru, Harich Kim, Dorn Harry C, Gibson Harry W

机构信息

Chemistry Department, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061, USA.

出版信息

Org Lett. 2009 Apr 16;11(8):1753-6. doi: 10.1021/ol9002527.

DOI:10.1021/ol9002527

PMID:19309087

Abstract

Two new 6,6-open phenyl-C(81)-butyric acid methyl ester metallofulleroids, M(3)N@C(80)PCBM (M = Sc, Y), were synthesized by diazoalkane addition reactions and fully characterized. The results demonstrate that the reactive sites are the same for M(3)N@C(80) (M = Sc, Y) but dramatically different from that of C(60).

摘要

通过重氮烷加成反应合成了两种新型的6,6-开环苯基-C(81)-丁酸甲酯金属富勒烯化合物，M(3)N@C(80)PCBM（M = Sc，Y），并对其进行了全面表征。结果表明，M(3)N@C(80)（M = Sc，Y）的反应位点相同，但与C(60)的反应位点有显著差异。