使用锌（II）模板高效两步合成无金属酞菁。
An efficient two-step synthesis of metal-free phthalocyanines using a Zn(ii) template.
作者信息
Alzeer Jawad, Roth Phillipe J C, Luedtke Nathan W
机构信息
Institute of Organic Chemistry, University of Zürich, Winterthurerstrasse 190, CH-8057, Zürich, Switzerland.
出版信息
Chem Commun (Camb). 2009 Apr 21(15):1970-1. doi: 10.1039/b822985f. Epub 2009 Mar 11.
DOI:10.1039/b822985f
PMID:19333460
Abstract
A new family of cationic phthalocyanines containing four guanidinium groups was synthesized in pyridine-HCl at 120 degrees C; under these conditions zinc was removed from both the starting materials and products to reveal a new synthetic route to metal-free phthalocyanines.
摘要
在120摄氏度的吡啶 - 盐酸中合成了一种含有四个胍基的新型阳离子酞菁；在这些条件下，锌从起始原料和产物中被除去，从而揭示了一种合成无金属酞菁的新途径。
Zotero 插件