氮杂环卡宾上的氢化物-溴化物交换：一种制备溴化铝烷和溴化镓烷的新途径。
Hydride-bromide exchange at an NHC-a new route to brominated alanes and gallanes.
作者信息
Alexander Sean G, Cole Marcus L, Furfari Samantha K, Kloth Marc
机构信息
School of Chemistry and Physics, University of Adelaide, Adelaide, SA 5005, Australia.
出版信息
Dalton Trans. 2009 Apr 28(16):2909-11. doi: 10.1039/b821367d. Epub 2009 Feb 18.
DOI:10.1039/b821367d
PMID:19352516
Abstract
The reaction of [MH(3)(Quinuclidine)] (M = Al or Ga) with an air stable dibrominated N-heterocyclic carbene (NHC) affords the hydride-bromide exchange product [MBr(2)H(NHC)].
摘要
[MH₃(奎宁环)]（M = Al或Ga）与一种空气稳定的二溴化N-杂环卡宾（NHC）反应，得到氢化物-溴化物交换产物[MBr₂H(NHC)]。
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