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[膜生物序批式反应器工艺中的膜污染特性及其控制]

[Characteristics of membrane fouling and its control in membrane sequencing batch reactor process].

作者信息

Zhang Sheng, Xu Li-rong, Li Hui-qin, Dong Xiao-lei, Zhang Ming-chuan, Zhu Jian-rong

机构信息

School of Environment, Beijing Normal University, Beijing 100875, China.

出版信息

Huan Jing Ke Xue. 2009 Jan;30(1):166-71.

Abstract

Characteristics of membrane fouling and its control were investigated using synthetic wastewater as feed in an anaerobic/aerobic membrane sequencing batch reactor (MSBR) for 300 days operational period. The experimental results showed that the sludge was in flocculent form, and the range of SVI was 64.6-110.6 mL x g(-1) during the initial 75 days operation. Membrane fouling occurred in a quick exponential growth, and the average growth rate of TMP was 0.309 kPa x d(-1). Membrane resistance was in the range of 0.393 x 10(11) - 1.298 x 10(11) m(-1) x d(-1) and specific membrane flux decreased from 4.4 L x (m2 x h x kPa) (-1) to 0.52 L x (m2 x h x kPa)(-1). The critical membrane flux was 20 L x (m2 x h)(-1) at 75th day. In 75-120 d operation, MSBR condition was regulated, and aerobic granular sludge in reactor appeared. SVI decreased steadily, and finally maintained approximately 40 mL x g(-1) from 170th day on. The sludge particle grew much gradually, and size distribution was mainly in diameter 500-1000 microm at 220th day. Membrane fouling developed very slowly. The average accumulating rate of TMP was only 0.062 kPa x d(-1) membrane resistance varied from 0.291 x 10(11) m(-1) x d(-1) to 0.404 x 10(11) m(-1) x d(-1), specific membrane flux decreased from 4.4 L x (m2 x h x kPa)(-1) to 1.4 L x (m2 x h x kPa) (-1) and critical membrane flux was 40 L x (m2 x h)(-1) at 220th day. These data clearly demonstrated that the formation of aerobic granular sludge was beneficial to cease the growth rate of membrane fouling. Specific membrane flux was the biggest at aeration strength of 100 m3 x (m2 x h)(-1) while membrane fouling rate was the lowest at aeration strength of 69 m3 x (m2 x h)(-1).

摘要

以合成废水为进水,在厌氧/好氧膜序批式反应器(MSBR)中运行300天,研究了膜污染特性及其控制方法。实验结果表明,污泥呈絮状,在运行初期的75天内,污泥体积指数(SVI)范围为64.6 - 110.6 mL·g⁻¹。膜污染呈快速指数增长,跨膜压差(TMP)的平均增长率为0.309 kPa·d⁻¹。膜阻力范围为0.393×10¹¹ - 1.298×10¹¹ m⁻¹·d⁻¹,比膜通量从4.4 L·(m²·h·kPa)⁻¹降至0.52 L·(m²·h·kPa)⁻¹。在第75天时,临界膜通量为20 L·(m²·h)⁻¹。在75 - 120天的运行期间,对MSBR条件进行了调节,反应器中出现了好氧颗粒污泥。SVI稳步下降,从第170天起最终稳定在约40 mL·g⁻¹。污泥颗粒逐渐长大,在第220天时,粒径分布主要在500 - 1000微米。膜污染发展非常缓慢。TMP的平均累积速率仅为0.062 kPa·d⁻¹,膜阻力在0.291×10¹¹ m⁻¹·d⁻¹至0.404×10¹¹ m⁻¹·d⁻¹之间变化,比膜通量从4.4 L·(m²·h·kPa)⁻¹降至1.4 L·(m²·h·kPa)⁻¹,在第220天时临界膜通量为40 L·(m²·h)⁻¹。这些数据清楚地表明,好氧颗粒污泥的形成有利于抑制膜污染的生长速率。曝气强度为100 m³·(m²·h)⁻¹时比膜通量最大,曝气强度为6九m³·(m²·h)⁻¹时膜污染速率最低。 (注:原文中“69 m3 x (m2 x h)(-1)”可能有误,推测为“69 m³·(m²·h)⁻¹”,译文按此推测翻译)

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