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关于纳米结构氧化铝的透明度:各向异性球体的瑞利-甘斯模型

On the transparency of nanostructured alumina: Rayleigh-Gans model for anisotropic spheres.

作者信息

Pecharromán Carlos, Mata-Osoro Gustavo, Díaz L Antonio, Torrecillas R, Moya J S

机构信息

Instituto de Ciencia de Materiales de Madrid, (CSIC), C/ Sor Juana Inés de la Cruz, 3, 28049 (Madrid), Spain.

出版信息

Opt Express. 2009 Apr 13;17(8):6899-912. doi: 10.1364/oe.17.006899.

Abstract

A light scattering model under the Rayleigh-Gans-Debye approximation has been developed for polycristalline alumina. The model states that transmittance of dense alumina ceramics basically depends not only on the maximum grain size but also on the preferential orientation of their c-axis, or texture. The effect of texture in transparency has been experimentally measured on several dense alumina samples with different grain size and compared to that obtained from x-ray Rietveld refinements with a very good agreement. The Rayleigh-Gans-Debye approximation also allows to represent optical data in a very simple way (logarithm of transmittance vs. the inverse of the wavelength square). Using these variables, a straight line is obtained for the Rayleigh-Gans-Debye approximation, its slope being proportional to the maximum grain size and textural parameter. Deviation from this law implies the presence of pores or grain of extremely large size.

摘要

已针对多晶氧化铝开发了一种在瑞利 - 甘斯 - 德拜近似下的光散射模型。该模型表明,致密氧化铝陶瓷的透射率不仅基本取决于最大晶粒尺寸,还取决于其c轴的择优取向,即织构。已通过实验测量了几种不同晶粒尺寸的致密氧化铝样品中织构对透明度的影响,并将其与通过X射线里特韦尔德精修获得的结果进行比较,二者吻合度很高。瑞利 - 甘斯 - 德拜近似还允许以非常简单的方式表示光学数据(透射率的对数与波长平方的倒数)。使用这些变量,对于瑞利 - 甘斯 - 德拜近似可得到一条直线,其斜率与最大晶粒尺寸和织构参数成正比。偏离该定律意味着存在孔隙或极大尺寸的晶粒。

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