Hua Rimao, Spliid Niels H, Heinrichson Kirsten, Laursen Bente
Key Lab of Agri-Food Safety of Anhui Province, College of Resource and Environmental Science, Anhui Agricultural University, 230036 Hefei, China.
Pest Manag Sci. 2009 Aug;65(8):857-61. doi: 10.1002/ps.1763.
Surfactants are very often used for more efficient pesticide spraying, but knowledge about their influence on the leaching potential for pesticides is very limited. In the present study, the leaching of the herbicide bentazone [3-isopropyl-1H-2, 1,3-benzothiadiazin-4(3H)-one 2,2-dioxide] was measured in columns with sandy loam soil with or without the addition of a non-ionic surfactant, octylphenol ethylene oxide condensate (Triton X-100, Triton), and an anionic surfactant, sodium dodecylbenzenesulfonate (SDBS), and in the presence of both surfactants (SDBS + Triton).
The mobility of bentazone (B) increased in the following order: B + Triton (slowest) < B + SDBS + Triton < B < B + SDBS (fastest). When Triton X-100 was applied to the soil together with bentazone, the leaching of bentazone in the soil decreased significantly compared with leaching of bentazone without the addition of surfactant. SDBS and Triton X-100 neutralised their influence on the leaching speed of bentazone in the soil columns when both surfactants were applied with bentazone.
From the study it can be concluded that, depending on their properties, surfactants can enhance or reduce the mobility of bentazone. By choosing a non-ionic surfactant, bentazone mobility can be reduced, giving time for degradation and thereby reducing the risk of groundwater pollution.
表面活性剂常用于更高效的农药喷洒,但关于它们对农药淋溶潜力影响的知识非常有限。在本研究中,在添加或不添加非离子表面活性剂辛基酚环氧乙烷缩合物(吐温X - 100,吐温)和阴离子表面活性剂十二烷基苯磺酸钠(SDBS)的砂壤土柱中,以及在两种表面活性剂(SDBS + 吐温)同时存在的情况下,测定了除草剂苯达松[3 - 异丙基 - 1H - 2,1,3 - 苯并噻二嗪 - 4(3H)- 酮2,2 - 二氧化物]的淋溶情况。
苯达松(B)的迁移率按以下顺序增加:B + 吐温(最慢)< B + SDBS + 吐温 < B < B + SDBS(最快)。当吐温X - 100与苯达松一起施用于土壤时,与不添加表面活性剂时苯达松的淋溶相比,土壤中苯达松的淋溶显著降低。当两种表面活性剂都与苯达松一起施用时,SDBS和吐温X - 100抵消了它们对土壤柱中苯达松淋溶速度的影响。
从该研究可以得出结论,根据其性质,表面活性剂可以增强或降低苯达松的迁移率。通过选择非离子表面活性剂,可以降低苯达松的迁移率,为其降解留出时间,从而降低地下水污染的风险。