Improvement of the platinum nanoparticles-carbon substrate interaction by insertion of a thiophenol molecular bridge.

The effect of thiophenol layer grafted on carbon for platinum catalyst stabilization was studied. The grafted layer was prepared by reduction of 4-thiophenoldiazonium ions in the presence of Vulcan XC72 substrate. The grafted layer was characterized by elemental analysis, thermogravimetric analysis coupled with mass spectrometry, and X-ray photoelectron spectroscopy. Platinum nanoparticles prepared by the "water in oil" microemulsion method were then deposited on modified substrates and bare Vulcan XC72. The platinum stability improvement was characterized by in situ X-ray diffraction and electrochemical aging. These experiments enabled to evidence a lower crystallite growth during heat treatment under hydrogen atmosphere and a lower active surface area loss for platinum particles deposited on modified substrates compared to those deposited on bare Vulcan XC72. This stability improvement can be attributed to a better interaction between platinum particles and carbon substrate due to the thiophenol molecular bridge.