金属有机框架化学中的二级建筑单元、网络及键合
Secondary building units, nets and bonding in the chemistry of metal-organic frameworks.
作者信息
Tranchemontagne David J, Mendoza-Cortés José L, O'Keeffe Michael, Yaghi Omar M
机构信息
Center for Reticular Chemistry, Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA.
出版信息
Chem Soc Rev. 2009 May;38(5):1257-83. doi: 10.1039/b817735j. Epub 2009 Mar 31.
This critical review presents a comprehensive study of transition-metal carboxylate clusters which may serve as secondary building units (SBUs) towards construction and synthesis of metal-organic frameworks (MOFs). We describe the geometries of 131 SBUs, their connectivity and composition. This contribution presents a comprehensive list of the wide variety of transition-metal carboxylate clusters which may serve as secondary building units (SBUs) in the construction and synthesis of metal-organic frameworks. The SBUs discussed here were obtained from a search of molecules and extended structures archived in the Cambridge Structure Database (CSD, version 5.28, January 2007) which included only crystals containing metal carboxylate linkages (241 references).
这篇综述文章全面研究了可作为金属有机框架（MOF）构建和合成二级结构单元（SBU）的过渡金属羧酸盐簇。我们描述了131种SBU的几何结构、连接方式和组成。本论文全面列出了种类繁多的过渡金属羧酸盐簇，它们可作为金属有机框架构建和合成中的二级结构单元。这里讨论的SBU是通过搜索剑桥结构数据库（CSD，2007年1月第5.28版）中存档的分子和扩展结构获得的，该数据库仅包含含有金属羧酸盐键的晶体（241篇参考文献）。
Zotero 插件