Leskes Michal, Madhu P K, Vega Shimon
Department of Chemical Physics, Weizmann Institute of Science, Rehovot, Israel.
J Magn Reson. 2009 Aug;199(2):208-13. doi: 10.1016/j.jmr.2009.05.003. Epub 2009 May 12.
Schemes such as phase-modulated Lee-Goldburg (PMLG) for homonuclear dipolar decoupling have been shown to yield high-resolution (1)H spectra at high magic-angle spinning (MAS) frequencies of 50-70kHz. This is at variance to the commonly held notion that these methods require MAS frequencies not comparable to the cycle frequencies of the pulse schemes. Here, a theoretical argument, based on bimodal Floquet theory, is presented to explain this aspect together with conditions where PMLG type of schemes may be successful at high MAS frequencies.
诸如用于同核偶极去耦的相位调制李-戈德堡(PMLG)等方案已被证明,在50 - 70kHz的高魔角旋转(MAS)频率下能产生高分辨率的¹H谱。这与通常认为的这些方法需要的MAS频率与脉冲方案的循环频率不相当的观念相矛盾。在此,基于双峰弗洛凯理论提出了一个理论论据,以解释这一方面以及PMLG类型的方案在高MAS频率下可能成功的条件。