将N₂还原为NH₃过程中的中间体：铁η²-肼基（1-）和二氮烯配合物的合成。

Intermediates in the reduction of N(2) to NH(3): synthesis of iron eta(2) hydrazido(1-) and diazene complexes.

作者信息

Crossland Justin L, Balesdent Chantal G, Tyler David R

机构信息

Department of Chemistry, University of Oregon, Eugene, Oregon 97403, USA.

出版信息

Dalton Trans. 2009 Jun 21(23):4420-2. doi: 10.1039/b902524c. Epub 2009 Apr 14.

DOI:10.1039/b902524c

PMID:19488434

Abstract

Iron complexes containing hydrazido(1-) and diazene ligands were investigated as potential intermediates in the reduction of N(2) to NH(3). Generation of cis-Fe(DMeOPrPE)(2)(eta(2)-N(2)H(3)) and cis-Fe(DMeOPrPE)(2)(eta(2)-N(2)H(2)) (DMeOPrPE = 1,2-bis(dimethoxypropylphosphino)ethane) was achieved by addition of base to cis-Fe(DMeOPrPE)(2)(N(2)H(4)). The hydrazine, hydrazido(1-), and diazene complexes can be interconverted by protonation/deprotonation reactions.

摘要

含肼基（1-）和二氮烯配体的铁配合物作为将N₂还原为NH₃的潜在中间体进行了研究。通过向顺式-[Fe(DMeOPrPE)₂(N₂H₄)]²⁺中加入碱，生成了顺式-[Fe(DMeOPrPE)₂(η²-N₂H₃)]⁺和顺式-Fe(DMeOPrPE)₂(η²-N₂H₂)（DMeOPrPE = 1,2-双（二甲氧基丙基膦基）乙烷）。肼、肼基（1-）和二氮烯配合物可通过质子化/去质子化反应相互转化。