Giusti Anna, Charron Gaëlle, Mazerat Sandra, Compain Jean-Daniel, Mialane Pierre, Dolbecq Anne, Rivière Eric, Wernsdorfer Wolfgang, Ngo Biboum Rosa, Keita Bineta, Nadjo Louis, Filoramo Arianna, Bourgoin Jean-Philippe, Mallah Talal
Institut de Chimie Moléculaire et des Matériaux d'Orsay, Université Paris-Sud 11, CNRS UMR 8182, 91405 Orsay, France.
Angew Chem Int Ed Engl. 2009;48(27):4949-52. doi: 10.1002/anie.200901806.
A POM to remember: Hexanuclear Fe(III) polyoxometalate (POM) single-molecule magnets (see structure) can be noncovalently assembled on the surface of single-wall carbon nanotubes. Complementary characterization techniques (see TEM image and magnetic hysteresis loops) demonstrate the integrity and bistability of the individual molecules, which could be used to construct single-molecule memory devices.
六核铁(III)多金属氧酸盐(POM)单分子磁体(见结构)可以非共价地组装在单壁碳纳米管表面。互补的表征技术(见透射电子显微镜图像和磁滞回线)证明了单个分子的完整性和双稳态,这可用于构建单分子存储器件。