Lee Min Hyung, Gao Hanwei, Odom Teri W
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, USA.
Nano Lett. 2009 Jul;9(7):2584-8. doi: 10.1021/nl900773m.
This letter describes the optical properties of quasi one-dimensional (1D) Au nanoslit arrays on a microscale pitch. The transmission spectra exhibited multiple minima that were well characterized by 1D surface plasmon polariton Bloch wave modes. We found that all higher order modes showed a linear response to small changes of refractive index (RI) with sensitivities up to 560 nm per RI unit, which is comparable to that of two-dimensional nanohole arrays. By calibrating the RI response of the nanoslit arrays, we could use the multiple modes to determine the RI of unknown, nonabsorbing solutions.
这封信描述了微尺度间距下准一维(1D)金纳米狭缝阵列的光学特性。透射光谱呈现出多个最小值,这些最小值由一维表面等离激元极化子布洛赫波模式很好地表征。我们发现,所有高阶模式对折射率(RI)的微小变化都呈现线性响应,灵敏度高达每RI单位560纳米,这与二维纳米孔阵列相当。通过校准纳米狭缝阵列的RI响应,我们可以利用多个模式来确定未知非吸收性溶液的RI。