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对称破缺相变过程中的旋节线辅助成核

Spinodal-assisted nucleation during symmetry-breaking phase transitions.

作者信息

Vega Daniel A, Gómez Leopoldo R

机构信息

Department of Physics, Universidad Nacional del Sur-CONICET, Av L.N. Além 1253, 8000 Bahía Blanca, Argentina.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2009 May;79(5 Pt 1):051607. doi: 10.1103/PhysRevE.79.051607. Epub 2009 May 29.

Abstract

The kinetics of spinodal-assisted crystallization in a region of the phase diagram where the dynamics is controlled by the critical slow down was studied by means of a Cahn-Hilliard model. The length-scale selectivity conducted by the spinodal process led to the formation of a filamentary network of density fluctuations that resemble the scarred states found in quantum-chaos systems. The present work reveals that the early structure of density fluctuations acts such as a precursor for crystallization and deeply affects the orientational and translational correlation between growing crystals. At deep quenches the network of fluctuations is deeply modified and the classical picture of spinodal decomposition is recovered.

摘要

利用Cahn-Hilliard模型研究了相图中动力学由临界减速控制区域内的旋节线辅助结晶动力学。旋节线过程进行的长度尺度选择性导致形成密度涨落的丝状网络,其类似于量子混沌系统中发现的疤痕态。目前的工作表明,密度涨落的早期结构起到了结晶前体的作用,并深刻影响生长晶体之间的取向和平移相关性。在深度淬火时,涨落网络被深度改变,旋节线分解的经典图像得以恢复。

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