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澄清污泥(碱性氧气转炉污泥)——一种用于从水溶液中去除铅(II)的吸附剂——动力学、热力学及解吸研究

Clarified sludge (basic oxygen furnace sludge)--an adsorbent for removal of Pb(II) from aqueous solutions--kinetics, thermodynamics and desorption studies.

作者信息

Naiya Tarun Kumar, Bhattacharya Ashim Kumar, Das Sudip Kumar

机构信息

Department of Chemical Engineering, University of Calcutta, Kolkata, West Bengal 700 009, India.

出版信息

J Hazard Mater. 2009 Oct 15;170(1):252-62. doi: 10.1016/j.jhazmat.2009.04.103. Epub 2009 May 4.

Abstract

The basic oxygen furnace waste generated in steel plant has been used as a low cost adsorbent for the removal of Pb(II) from aqueous solution. The effect of pH, adsorbent dosage, initial metal ion concentration, contact time and temperature on adsorption process was studied in batch experiments. Results of the equilibrium experiments showed that the solution pH was the key factor affecting the adsorption characteristics. Optimum pH for the adsorption was found to be 5 with corresponding adsorbent dosage level of 5 g/L. The equilibrium was achieved within 1h of contact time. Kinetics data were best described by pseudo second order model. The effective particle diffusion coefficient of Pb(II) is the order of 10(-10)m(2)/s. The maximum uptake was 92.5mg/g. The adsorption data can be well fitted by Freundlich isotherm. The result of the equilibrium studies showed that the solution pH was the key factor affecting the adsorption. External mass transfer analysis was also carried out for the adsorption process. The thermodynamic studies indicated that the adsorption is spontaneous and endothermic. The sorption energy (10.1745 kJ/mol) calculated from Dubinin-Radushkevich isotherm indicated that the adsorption process is chemical in nature. Desorption studies were carried out using dilute mineral acids to elucidate the mechanism of adsorption. Application studies were carried out considering the economic viewpoint of wastewater treatment plant operations.

摘要

钢铁厂产生的碱性氧气转炉废渣已被用作从水溶液中去除Pb(II)的低成本吸附剂。通过批量实验研究了pH值、吸附剂用量、初始金属离子浓度、接触时间和温度对吸附过程的影响。平衡实验结果表明,溶液pH值是影响吸附特性的关键因素。发现吸附的最佳pH值为5,相应的吸附剂用量水平为5 g/L。接触1小时内达到平衡。动力学数据用伪二级模型能得到最佳描述。Pb(II)的有效颗粒扩散系数约为10(-10)m(2)/s。最大吸附量为92.5mg/g。吸附数据能很好地拟合Freundlich等温线。平衡研究结果表明,溶液pH值是影响吸附的关键因素。还对吸附过程进行了外部传质分析。热力学研究表明,吸附是自发的且吸热。根据Dubinin-Radushkevich等温线计算的吸附能(10.1745 kJ/mol)表明吸附过程本质上是化学吸附。使用稀无机酸进行解吸研究以阐明吸附机理。从废水处理厂运营的经济角度进行了应用研究。

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