双铑六卟啉：[28]六卟啉的金属化及Hückel芳香-反芳香的平滑相互转化
Bis-rhodium hexaphyrins: metalation of [28]hexaphyrin and a smooth Hückel aromatic-antiaromatic interconversion.
作者信息
Rath Harapriya, Aratani Naoki, Lim Jong Min, Lee Jae Seok, Kim Dongho, Shinokubo Hiroshi, Osuka Atsuhiro
机构信息
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan.
出版信息
Chem Commun (Camb). 2009 Jul 7(25):3762-4. doi: 10.1039/b905859a. Epub 2009 May 12.
DOI:10.1039/b905859a
PMID:19557274
Abstract
Metalation of [28]hexaphyrin(1.1.1.1.1.1) with RhCl(CO)(2) resulted in the formation of an antiaromatic bis-Rh(i) complex, which can be oxidized to an aromatic bis-Rh(i) complex with retention of its rectangular structure.
摘要
[28]六卟啉（1.1.1.1.1.1）与二氯（羰基）铑（Ⅰ）（RhCl(CO)(2)）发生金属化反应，生成了一种反芳香性的双铑（Ⅰ）配合物，该配合物可被氧化为芳香性双铑（Ⅰ）配合物，同时保持其矩形结构。
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