Nishimoto Shunsuke, Sekine Hitomi, Zhang Xintong, Liu Zhaoyue, Nakata Kazuya, Murakami Taketoshi, Koide Yoshihiro, Fujishima Akira
Kanagawa Academy of Science and Technology, KSP Building West 614, 3-2-1 Sakado, Takatsu-ku, Kawasaki 213-0012, Japan.
Langmuir. 2009 Jul 7;25(13):7226-8. doi: 10.1021/la9011372.
A renewable superhydrophobic-superhydrophilic pattern with a minimum dimension of 50 microm is prepared from octadecyltrimethoxysilane self-assembled monolayer-covered superhydrophobic Al2O3 overlayers on a superhydrophilic TiO2 surface via self-assembly and calcination of boehmite (AlOOH.nH2O) particles. The resulting Al2O3 layer plays dual roles as a superhydrophobic layer and as a UV-blocking layer for the underlying TiO2.
通过对勃姆石(AlOOH·nH₂O)颗粒进行自组装和煅烧,在超亲水的TiO₂表面制备了一种最小尺寸为50微米的可再生超疏水-超亲水图案,该图案由十八烷基三甲氧基硅烷自组装单层覆盖的超疏水Al₂O₃覆盖层构成。所得的Al₂O₃层对下层的TiO₂起到超疏水层和紫外线阻挡层的双重作用。