Chatterjee Debarati, Cherayil Binny J
Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India.
Phys Rev E Stat Nonlin Soft Matter Phys. 2009 Jul;80(1 Pt 1):011118. doi: 10.1103/PhysRevE.80.011118. Epub 2009 Jul 14.
A recent theoretical model developed by Imparato [Phys. Rev. E 76, 050101(R) (2007)] of the experimentally measured heat and work effects produced by the thermal fluctuations of single micron-sized polystyrene beads in stationary and moving optical traps has proved to be quite successful in rationalizing the observed experimental data. The model, based on the overdamped Brownian dynamics of a particle in a harmonic potential that moves at a constant speed under a time-dependent force, is used to obtain an approximate expression for the distribution of the heat dissipated by the particle at long times. In this paper, we generalize the above model to consider particle dynamics in the presence of colored noise, without passing to the overdamped limit, as a way of modeling experimental situations in which the fluctuations of the medium exhibit long-lived temporal correlations, of the kind characteristic of polymeric solutions, for instance, or of similar viscoelastic fluids. Although we have not been able to find an expression for the heat distribution itself, we do obtain exact expressions for its mean and variance, both for the static and for the moving trap cases. These moments are valid for arbitrary times and they also hold in the inertial regime, but they reduce exactly to the results of Imparato in appropriate limits.
因帕拉托[《物理评论E》76, 050101(R) (2007)]最近开发的一个理论模型,用于解释在固定和移动光阱中单个微米级聚苯乙烯珠热涨落产生的热效应和功效应的实验测量结果,该模型在合理解释观测到的实验数据方面已被证明相当成功。该模型基于粒子在简谐势中过阻尼布朗动力学,粒子在随时间变化的力作用下以恒定速度移动,用于获得粒子在长时间内耗散热量分布的近似表达式。在本文中,我们推广上述模型,考虑存在有色噪声时的粒子动力学,而不采用过阻尼极限,以此来模拟实验情况,例如介质涨落呈现聚合物溶液或类似粘弹性流体特征的那种长寿命时间相关性。尽管我们未能找到热量分布本身的表达式,但我们确实得到了其均值和方差的精确表达式,包括静态和移动光阱情况。这些矩在任意时间都有效,并且在惯性区域也成立,但在适当极限下它们精确地简化为因帕拉托的结果。