对苯二甲酸铬金属有机骨架材料MIL-101上四氢化萘的选择性氧化反应
Selective oxidation of tetralin over a chromium terephthalate metal organic framework, MIL-101.
作者信息
Kim Jun, Bhattacharjee Samiran, Jeong Kwang-Eun, Jeong Soon-Yong, Ahn Wha-Seung
机构信息
Department of Chemical Engineering, Inha University, Incheon, Korea.
出版信息
Chem Commun (Camb). 2009 Jul 14(26):3904-6. doi: 10.1039/b902699a. Epub 2009 Jun 3.
DOI:10.1039/b902699a
PMID:19662247
Abstract
MIL-101, a mesoporous chromium terephthalate metal organic framework, was found to be an efficient heterogeneous catalyst for selective oxidation of tetralin to 1-tetralone using tert-butyl hydroperoxide or acylperoxy radicals generated in situ from trimethylacetaldehyde and O(2) as an oxidant.
摘要
MIL-101是一种介孔对苯二甲酸铬金属有机骨架材料，被发现是一种高效的多相催化剂，可使用叔丁基过氧化氢或由三甲基乙醛原位生成的酰基过氧自由基以及O(2)作为氧化剂，将萘满选择性氧化为1-萘满酮。
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