Zhang Lifei, Dong Liang, Shi Shuangxin, Zhou Li, Zhang Ting, Huang Yeru
State Environmental Protection Key Laboratory of Dioxin Pollution Control, National Research Center for Environmental Analysis and Measurement, No. 1 Yuhui Nanlu, Chaoyang District, Beijing 100029, China.
Chemosphere. 2009 Oct;77(5):628-33. doi: 10.1016/j.chemosphere.2009.08.055. Epub 2009 Sep 20.
The present article attempts to investigate organochlorine pesticides' (OCPs) contamination in soils from polluted sites and to assess the soil quality in the study area. HCHs and eight other persistent organic pollutants (POPs) pesticides were studied in surface soil samples collected from a new (F) and an old (G) pesticide factory in Southeast China. According to the measured results, surface soils from F and G were contaminated with HCHs, DDTs, HCB, and chlordane, with beta-HCH and p,p'-DDT being the two dominant substances. The total OCPs concentrations of surface soils from F and G were 0.84 and 166mgkg(-1) respectively. Cluster analysis was performed to group the soil sites in terms of their total OCPs contamination levels. The ratios of alpha-HCH/gamma-HCH, o,p'-DDT/p,p'-DDT, and trans-/cis- chlordane in some of the soil samples are similar to their technical products in the study area which indicates the lack of hazardous waste management practices of the pesticide production and transportation. According to GB 15618-1995, the HCHs could be classified as light pollution and little pollution for F and G, whereas DDTs levels of F and G could be defined as little pollution and heavy pollution, respectively. This study indicates that surface soils, especially residential area soils from F and G were facing varying degrees of pollutions. The situation is more hazardous due to the continuous exposure of the population that lives in the surroundings. Therefore, on-site remediation technologies and the best available techniques/best environmental practices (BAT/BEP) should be carried out on these factories with the national implementation of the Stockholm Convention.
本文旨在调查污染场地土壤中的有机氯农药(OCPs)污染情况,并评估研究区域的土壤质量。在中国东南部一家新建(F)和一家旧有(G)农药厂采集的表层土壤样本中,研究了六氯环己烷(HCHs)和其他八种持久性有机污染物(POPs)农药。根据测量结果,F厂和G厂的表层土壤受到六氯环己烷、滴滴涕(DDTs)、六氯苯(HCB)和氯丹的污染,其中β-六氯环己烷和p,p'-滴滴涕是两种主要污染物。F厂和G厂表层土壤中OCPs的总浓度分别为0.84和166mg/kg。进行聚类分析,以便根据土壤场地的总OCPs污染水平对其进行分组。一些土壤样本中α-六氯环己烷/γ-六氯环己烷、o,p'-滴滴涕/p,p'-滴滴涕和反式/顺式氯丹的比例与研究区域的工业产品相似,这表明农药生产和运输过程中缺乏危险废物管理措施。根据GB 15618-1995标准,F厂和G厂的六氯环己烷可分别归类为轻度污染和轻度污染,而F厂和G厂的滴滴涕水平可分别定义为轻度污染和重度污染。本研究表明,表层土壤,尤其是F厂和G厂居民区的土壤面临着不同程度的污染。由于周围居民的持续接触,这种情况更加危险。因此,随着《斯德哥尔摩公约》在全国的实施,应在这些工厂实施现场修复技术和最佳可行技术/最佳环境实践(BAT/BEP)。