Liu Yu-yan, Liu Min, Cheng Shu-bo
Department of Geography, East China Normal University, Shanghai 200062, China.
Huan Jing Ke Xue. 2009 Oct 15;30(10):3050-4.
In order to study accumulation characteristics of PGEs in multimedia from road environment, samples of road dust, roadside soil and plant were collected from five roads in Shanghai, and were analysed by ICP-MS following aqua regia digestion. The results are as following: average concentrations of Rh, Pd and Pt were 24.92, 88.39, 22.28 ng/g in dust, 3.64, 17.45, 0.97 ng/g in soil and 2.66, 6.39, 0.57 ng/g in plant, respectively. The concentrations of PGEs in dust were higher than that in soil and in plant. Meanwhile, PGEs concentrations in plant were lower than that in dust, and closed to that of soil. The implementation of the automobile emission standard only in central city of Shanghai didn't cause obvious correlation between PGEs in multimedia and traffic volume. The plant adsorption capacity for PGEs of road dust showed: Pt > Pd > Rh, while its absorptive capacity for PGEs of soil was: Pd > Rh > Pt. PGEs ratios in multimedia were not completely coincident but in the range of PGEs ratios of road dust in Shanghai, which indicated a common traffic-related source of these metals.
为研究道路环境中多介质中铂族元素(PGEs)的累积特征,采集了上海五条道路的道路灰尘、路边土壤和植物样本,采用王水消解后用ICP-MS进行分析。结果如下:灰尘中铑(Rh)、钯(Pd)和铂(Pt)的平均浓度分别为24.92、88.39、22.28 ng/g,土壤中分别为3.64、17.45、0.97 ng/g,植物中分别为2.66、6.39、0.57 ng/g。PGEs在灰尘中的浓度高于土壤和植物中的浓度。同时,PGEs在植物中的浓度低于灰尘中的浓度,且与土壤中的浓度相近。仅在上海中心城区实施汽车排放标准并未导致多介质中PGEs与交通流量之间存在明显相关性。道路灰尘中PGEs的植物吸附能力表现为:Pt>Pd>Rh,而土壤中PGEs的吸附能力为:Pd>Rh>Pt。多介质中PGEs的比值并不完全一致,但在上海道路灰尘PGEs比值范围内,这表明这些金属具有共同的交通相关来源。