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碳纤维增强的微波热修复原油污染土壤。

Microwave thermal remediation of crude oil contaminated soil enhanced by carbon fiber.

机构信息

Key Laboratory of Industrial Ecology and Environmental Engineering, Ministry of Education of China, School of Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024, China.

出版信息

J Environ Sci (China). 2009;21(9):1290-5. doi: 10.1016/s1001-0742(08)62417-1.

Abstract

Thermal remediation of the soil contaminated with crude oil using microwave heating enhanced by carbon fiber (CF) was explored. The contaminated soil was treated with 2.45 GHz microwave, and CF was added to improve the conversion of microwave energy into thermal energy to heat the soil. During microwave heating, the oil contaminant was removed from the soil matrix and recovered by a condensation system of ice-salt bath. The experimental results indicated that CF could efficiently enhance the microwave heating of soil even with relatively low-dose. With 0.1 wt.% CF, the soil could be heated to approximately 700 degrees C within 4 min using 800 W of microwave irradiation. Correspondingly, the contaminated soil could be highly cleaned up in a short time. Investigation of oil recovery showed that, during the remediation process, oil contaminant in the soil could be efficiently recovered without causing significant secondary pollution.

摘要

采用碳纤维(CF)增强的微波加热对受原油污染的土壤进行了热修复研究。用 2.45GHz 微波处理受污染的土壤,并添加 CF 以提高微波能量向热能的转化效率,从而加热土壤。在微波加热过程中,油污染物从土壤基质中被去除,并通过冰盐浴的冷凝系统回收。实验结果表明,CF 可以有效地增强土壤的微波加热效果,即使添加量相对较低也是如此。在 0.1wt.%CF 的情况下,使用 800W 的微波辐射,土壤可以在 4 分钟内加热到大约 700°C。相应地,受污染的土壤可以在短时间内得到高效清洁。对油回收的研究表明,在修复过程中,土壤中的油污染物可以被有效地回收,而不会造成明显的二次污染。

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