Synthesis and spectral investigations of Mn(II) complexes of pentadentate bis(thiosemicarbazones).

Five Mn(II) complexes of bis(thiosemicarbazones) which are represented as [Mn(H(2)Ac4Ph)Cl(2)] (1), [Mn(Ac4Ph)H(2)O] (2), [Mn(H(2)Ac4Cy)Cl(2)].H(2)O (3), [Mn(H(2)Ac4Et)Cl(2)].3H(2)O (4) and [Mn(H(2)Ac4Et)(OAc)(2)].3H(2)O (5) have been synthesized and characterized by elemental analyses, electronic, infrared and EPR spectral techniques. In all the complexes except [Mn(Ac4Ph)H(2)O], the ligands act as pentadentate neutral molecules and coordinate to Mn(II) ion through two thione sulfur atoms, two azomethine nitrogens and the pyridine nitrogen, suggesting a heptacoordination. While in compound [Mn(Ac4Ph)H(2)O], the dianionic ligand is coordinated to the metal suggesting six coordination in this case. Magnetic studies indicate the high spin state of Mn(II). Conductivity measurements reveal their non-electrolyte nature. EPR studies indicate five g values for [Mn(Ac4Ph)H(2)O] showing zero field splitting.