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氟化物增强的镧系元素发光和多功能 Al3Ln2(Ln = Nd、Eu、Yb)杂五核配合物的白光发射。

Fluoride-enhanced lanthanide luminescence and white-light emitting in multifunctional Al3Ln2 (Ln = Nd, Eu, Yb) heteropentanuclear complexes.

机构信息

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.

出版信息

Chem Commun (Camb). 2009 Dec 21(47):7318-20. doi: 10.1039/b912474h. Epub 2009 Nov 2.

Abstract

Multifunctional heteropentanuclear Al(3)Ln(2) (Ln = Nd, Eu, Yb) clusters with a novel structure exhibit significantly fluoride-enhanced lanthanide emission intensity and lifetime in both solid state and solution as well as unusual white-light emitting for an Al(3)Eu(2) complex.

摘要

具有新颖结构的多功能杂戊核 Al(3)Ln(2)(Ln = Nd、Eu、Yb)簇在固态和溶液中均表现出显著的氟化物增强镧系元素发射强度和寿命,以及 Al(3)Eu(2)配合物的不寻常的白光发射。

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