Università degli Studi di Genova, Dipartimento di Chimica e Chimica Industriale, Via Dodecaneso 31, 16146 Genova, Italy.
Phys Chem Chem Phys. 2009 Dec 28;11(48):11515-9. doi: 10.1039/b910734g. Epub 2009 Oct 22.
In this work, we report on the optical properties and amplified spontaneous emissions (ASE) of polystyrene opals engineered with planar structural defects containing a conjugated polymer emitter. Defects in opals give rise to allowed states inside the photonic stop band, which are probed by transmittance and reflectance spectroscopy. The emission spectrum of the polymer embedded in the defect layer is strongly modified and fingerprints of defect states located inside the stop band are recognized. Amplified spontaneous emission for these engineered photonic crystals is clearly observed.
在这项工作中,我们报告了具有包含共轭聚合物发射器的平面结构缺陷的聚苯乙烯opal 的光学性质和放大自发发射(ASE)。opal 中的缺陷会导致光子带隙内的允许态,这些态可以通过透射和反射光谱来探测。嵌入在缺陷层中的聚合物的发射光谱被强烈修饰,并识别出位于带隙内的缺陷态的特征。这些工程光子晶体的放大自发发射被清楚地观察到。