College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006, PR China.
J Hazard Mater. 2010 Apr 15;176(1-3):597-601. doi: 10.1016/j.jhazmat.2009.11.071. Epub 2009 Nov 20.
The study reports the minimization of excess sludge produced in the membrane bioreactor (MBR) coupled with a sludge Fenton oxidation (oxidation using H(2)O(2) with an iron catalyst) process. Total experimental period was divided into two stages. At the first stage, a series of batch studies were carried out to elucidate the parameters governing the activated sludge disintegration. It was found that Fenton oxidation can disrupt the cell walls and cause the release of plasm from the cells, thus increasing the content of soluble organics and soluble nitrogen in the solution. At the following stage, two MBRs with and without the Fenton process were operated to evaluate the influence of sludge Fenton oxidation on the sludge yield and water quality. It was demonstrated that the incorporation of Fenton process can significantly reduce sludge production, as evidenced from the decrease in the value of the average sludge yield from 0.15 to 0.006 g MLSS/g COD. The water quality of effluent in both systems was maintained at a satisfactory level. Furthermore, it was revealed that the MBR system with the sludge Fenton oxidation process showed relatively better performance for TN removal than that without it.
该研究报告了膜生物反应器(MBR)与污泥芬顿氧化(使用铁催化剂的 H(2)O(2)氧化)工艺相结合时产生的剩余污泥的最小化。总实验期分为两个阶段。在第一阶段,进行了一系列批处理研究,以阐明控制活性污泥解体的参数。结果发现,芬顿氧化可以破坏细胞壁并导致细胞质从细胞中释放,从而增加溶液中可溶性有机物和可溶性氮的含量。在接下来的阶段,运行了两个带有和不带有芬顿工艺的 MBR 以评估污泥芬顿氧化对污泥产率和水质的影响。结果表明,芬顿工艺的加入可以显著减少污泥的产生,这可以从平均污泥产率从 0.15 降低到 0.006 g MLSS/g COD 得到证明。两个系统的出水水质均保持在令人满意的水平。此外,结果表明,带有污泥芬顿氧化工艺的 MBR 系统在 TN 去除方面的性能优于没有该工艺的系统。