Liu Zongyuan, Liu Sheng, Wang Kai, Luo Xiaobing
School of Mechanical Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.
Appl Opt. 2010 Jan 10;49(2):247-57. doi: 10.1364/AO.49.000247.
The optical properties of YAG:Ce phosphor were measured by a double-integrating-sphere system and calculated by Mie theory and Monte Carlo ray tracing to provide precise optical characterizations of YAG:Ce phosphor for white light-emitting diode (LED) packaging design. Measurement results showed that the phosphor presents strong absorption for blue light, high reflection for yellow light, and an isotropic emission pattern of converted light. The conversion efficiency and quantum efficiency for the saturated phosphor are around 70% and 87%, respectively. Based on the measurement results, the absorption coefficient, scattering coefficient, and anisotropy factor of the phosphor calculated by Mie theory were compared with those calculated by ray-tracing simulation to modify Mie theory to find a reasonable method that can easily obtain the optical constants of YAG:Ce phosphor. Comparisons revealed that Mie theory can predict the variation of the optical constants of phosphor, but the absorption and scattering cross sections should be multiplied with two fitting parameters. The fitting parameters have been given in this study and can be obtained by testing packaged LEDs with different phosphor concentrations.
采用双积分球系统测量了YAG:Ce荧光粉的光学特性,并通过米氏理论和蒙特卡罗光线追踪进行计算,以提供用于白光发光二极管(LED)封装设计的YAG:Ce荧光粉精确的光学特性描述。测量结果表明,该荧光粉对蓝光有强烈吸收,对黄光有高反射,且转换光呈各向同性发射模式。饱和荧光粉的转换效率和量子效率分别约为70%和87%。基于测量结果,将米氏理论计算的荧光粉吸收系数、散射系数和各向异性因子与光线追踪模拟计算的结果进行比较,对米氏理论进行修正,以找到一种能轻松获得YAG:Ce荧光粉光学常数的合理方法。比较结果表明,米氏理论可以预测荧光粉光学常数的变化,但吸收和散射截面应乘以两个拟合参数。本研究给出了拟合参数,可通过测试不同荧光粉浓度的封装LED来获得。