Xu Jing, Ren Ming-Zhong, Du Gou-Yong, Zhang Su-Kun, Xu Zhen-Cheng
School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China.
Huan Jing Ke Xue. 2009 Nov;30(11):3269-75.
In the present study, 16 polycyclic aromatic hydrocarbons (PAHs) in the surface sediment from Beijiang River in China were quantitatively determined by GC/MS. The concentration of PAHs varied from 38.2 to 6470 ng x g(-1) dry weight, with average 1071 ng x g(-1), which was in moderate level compared with other rivers in Pear River Basin. The PAHs distribution in Bejiang River was obviously affected by point source emissions. The high PAHs concentrations of 6470 ng x g(-1) and 4 470 ng x g(-1) were found at the outfalls of Shaoye and the Shakou town, respectively, where PAHs probably derived from local mining/smelting and related industrial actives. The ecological risk of surface sediment in Beijiang River was assessed with the methods of sediment quality guidelines (SQGs), sediment quality standards (SQSs) and contamination factors (CFs) . The result shows that the adverse biological toxicity effect might occasionally happen in more than half of sampling stations. By comparison with the background area, the contamination degrees of PAHs in 20 sampling stations were at very high level, which should arrest the local governments' attentions. The highest ecological risk areas occurred at the outfalls of Shaoye and the Shakou town in which the ecological risks derived from PAHs were within between probable effect level (PEL) and frequent effect level (FEL). The future research was suggested mainly focusing on the status of benthos, sources of pollutants and ways to control pollution in high-risk areas.
在本研究中,采用气相色谱/质谱联用仪(GC/MS)对中国北江表层沉积物中的16种多环芳烃(PAHs)进行了定量测定。PAHs的浓度在38.2至6470 ng x g(-1)干重之间变化,平均为1071 ng x g(-1),与珠江流域的其他河流相比处于中等水平。北江PAHs的分布明显受到点源排放的影响。在韶关和沙口镇的排污口分别发现了高达6470 ng x g(-1)和4470 ng x g(-1)的PAHs高浓度,这些PAHs可能源自当地的采矿/冶炼及相关工业活动。采用沉积物质量准则(SQGs)、沉积物质量标准(SQSs)和污染因子(CFs)方法对北江表层沉积物的生态风险进行了评估。结果表明,超过半数的采样站偶尔可能会出现不利的生物毒性效应。与背景区域相比,20个采样站的PAHs污染程度处于非常高的水平,应引起当地政府的关注。最高生态风险区域出现在韶关和沙口镇的排污口,其中PAHs产生的生态风险处于可能效应水平(PEL)和频繁效应水平(FEL)之间。建议未来的研究主要集中在底栖生物的状况、污染物来源以及高风险区域的污染控制方法上。