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对来自公元前和缅因州的 Pleistocene 藤壶进行 ESR 测年:一种追踪海平面变化的新方法。

ESR dating pleistocene barnacles from BC and Maine: a new method for tracking sea level change.

机构信息

Department of Chemistry, Williams College, Williamstown, MA 01267, USA.

出版信息

Health Phys. 2010 Feb;98(2):417-26. doi: 10.1097/HP.0b013e3181aadce1.

Abstract

Barnacles have never been successfully dated by electron spin resonance (ESR). Living mainly in the intertidal zone, barnacles die when sea level changes cause their permanent exposure. Thus, dating the barnacles dates past sea level changes. From this, we can measure apparent sea level changes that occur due to ocean volume changes, crustal isostasy, and tectonics. ESR can date aragonitic mollusc shells ranging in age from 5 ka to at least 500 ka. By modifying the standard ESR method for molluscs to chemically dissolve 20 microm from off the shells, six barnacle samples from Norridgewock, Maine, and Khyex River, British Columbia, were tested for suitability for ESR dating. Due to Mn2+ interference peaks, the four Maine barnacle samples were not datable by ESR. Two barnacles from BC, which lacked Mn2+ interference, yielded a mean ESR age of 15.1 +/- 1.0 ka. These ages agree well with 14C dates on the barnacles themselves and wood in the overlying glaciomarine sediment. Although stability tests to calculate the mean dating signal lifetime and more ESR calibration tests against other barnacles of known age are needed to ensure the method's accuracy, ESR can indeed date Balanus, and thus, sea level changes.

摘要

藤壶从未通过电子自旋共振 (ESR) 成功定年。藤壶主要生活在潮间带,当海平面变化导致其永久暴露时,它们就会死亡。因此,通过藤壶可以追溯过去的海平面变化。由此,我们可以测量由于海洋体积变化、地壳均衡和构造引起的海平面表观变化。ESR 可以对年龄在 5ka 至至少 500ka 的文石质软体动物贝壳进行定年。通过修改用于软体动物的标准 ESR 方法,从贝壳上化学溶解 20 微米,可以对来自缅因州诺里基沃克和不列颠哥伦比亚省 KhyeX 河的六个藤壶样本进行 ESR 定年适用性测试。由于 Mn2+ 干扰峰,缅因州的四个藤壶样本无法通过 ESR 定年。来自 BC 的两个没有 Mn2+干扰的藤壶产生了 15.1 +/- 1.0ka 的平均 ESR 年龄。这些年龄与藤壶本身和覆盖其上的冰川海洋沉积物中的木材的 14C 日期非常吻合。尽管需要进行稳定性测试以计算平均定年信号寿命,并对其他具有已知年龄的藤壶进行更多的 ESR 校准测试,以确保该方法的准确性,但 ESR 确实可以对藤壶进行定年,从而对海平面变化进行定年。

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