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采用振膜超滤法从金属加工乳液中分离水。

Separation of water from metal working emulsions by ultrafiltration using vibratory membranes.

机构信息

LPT2R, University Yahia Fares, Ain D'Heb, 26001 Medea, Algeria.

出版信息

J Hazard Mater. 2010 May 15;177(1-3):978-82. doi: 10.1016/j.jhazmat.2010.01.014. Epub 2010 Jan 11.

Abstract

In this paper, we investigate the application of a vibratory shear-enhanced filtration system (VSEP) to separation of water from oil-in-water emulsions. The VSEP module consists in an annular membrane of 500 cm(2) area which oscillates azimuthally in its own plane with an amplitude depending upon frequency. Polyethersulfone (PES) membranes of 50 and 20 kDa were used. Test fluids consisted of oil-in-water emulsion at an oil concentration of 4% prepared from a concentrated cutting fluid. The critical flux for stable operation was investigated by increasing the permeate flux in steps while monitoring the transmembrane pressure (TMP). With a 50 kDa membrane the flux increased nonlinearly with TMP and reached 250 L h(-1)m(-2) at a TMP of 1500 kPa while permeate turbidity decayed from 1.8 to 0.9 NTU above 600 kPa from an initial emulsion turbidity of 21,900 NTU. With the 20 kDa membrane, the flux increased linearly with TMP until 1600 kPa, but the oil concentration in permeate became negligible (turbidity near zero NTU). Concentration tests showed that the flux decreased linearly with ln(VRR) where VRR is the volume reduction ratio while permeate turbidity increased exponentially to 25NTU above a VRR of 4. This work confirms the high performance of the VSEP for oil separation from water in metal working emulsions.

摘要

本文研究了振动剪切增强过滤系统(VSEP)在水包油乳液分离中的应用。VSEP 模块由一个 500cm² 的环形膜组成,该膜在其自身平面内以取决于频率的幅度进行轴向振动。使用了 50 和 20 kDa 的聚醚砜(PES)膜。测试液为 4%油浓度的水包油乳液,由浓缩切削液制备。通过逐步增加渗透通量并监测跨膜压力(TMP)来研究稳定操作的临界通量。对于 50 kDa 的膜,通量随 TMP 非线性增加,在 TMP 为 1500 kPa 时达到 250 L h-1 m-2,而在初始乳液浊度为 21900 NTU 的情况下,渗透浊度从 600 kPa 以上的 1.8 下降到 0.9 NTU。对于 20 kDa 的膜,通量随 TMP 线性增加,直到 1600 kPa,但渗透物中的油浓度变得可以忽略不计(浊度接近零 NTU)。浓缩测试表明,通量随 ln(VRR)线性下降,其中 VRR 是体积减少比,而渗透浊度在 VRR 超过 4 时呈指数增加到 25NTU。这项工作证实了 VSEP 在从金属加工乳液中分离油方面的高性能。

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