寡硅烷锌化合物的合成及结构多样性。
Synthesis and structural diversity of oligosilanylzinc compounds.
机构信息
Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 16, 8010, Graz, Austria.
出版信息
Dalton Trans. 2010 Feb 14;39(6):1598-603. doi: 10.1039/b910463a. Epub 2009 Dec 10.
DOI:10.1039/b910463a
PMID:20104323
Abstract
Reactions of potassium oligosilanyls with ZnCl(2) lead to the formation of oligosilanylzinc compounds with zinc's coordination sphere expanded by ligation of TMEDA, an additional oligosilanyl group, or a chloride ion.
摘要
钾聚硅烷与 ZnCl(2)反应生成聚硅烷锌化合物，锌的配位层通过 TMEDA、额外的聚硅烷基或氯离子的配位而扩展。
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