胺与 η(2)(C,O)-η(1)(O)-配位醛的席夫缩合反应中出乎意料的化学选择性。
Unexpected chemoselectivity in the Schiff condensation of amines with eta(2)(C,O)- eta(1)(O)-coordinated aldehyde.
机构信息
IU CINQUIMA, Química Inorgánica, Universidad de Valladolid, E-47005, Valladolid, Spain.
出版信息
Dalton Trans. 2010 Feb 7;39(5):1201-3. doi: 10.1039/b921892k. Epub 2009 Nov 17.
DOI:10.1039/b921892k
PMID:20104345
Abstract
The aldehyde function coordinated as eta(1); eta(2) is able to discriminate between aliphatic and aromatic amines in the Schiff condensation reaction.
摘要
作为 η(1);η(2) 配位的醛基能够在希夫缩合反应中区分脂肪族和芳香族胺。
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