College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China.
J Zhejiang Univ Sci B. 2010 Feb;11(2):87-93. doi: 10.1631/jzus.B0900272.
A sequential anode-cathode double-chamber microbial fuel cell (MFC), in which the effluent of anode chamber was used as a continuous feed for an aerated cathode chamber, was constructed in this experiment to investigate the performance of brewery wastewater treatment in conjugation with electricity generation. Carbon fiber was used as anode and plain carbon felt with biofilm as cathode. When hydraulic retention time (HRT) was 14.7 h, a relatively high chemical oxygen demand (COD) removal efficiency of 91.7%-95.7% was achieved under long-term stable operation. The MFC displayed an open circuit voltage of 0.434 V and a maximum power density of 830 mW/m(3) at an external resistance of 300 Omega. To estimate the electrochemical performance of the MFC, electrochemical measurements were carried out and showed that polarization resistance of anode was the major limiting factor in the MFC. Since a high COD removal efficiency was achieved, we conclude that the sequential anode-cathode MFC constructed with bio-cathode in this experiment could provide a new approach for brewery wastewater treatment.
本实验构建了一种顺序式阳极-阴极双室微生物燃料电池(MFC),其中阳极室的出水被用作充气阴极室的连续进料,以研究与发电相结合的啤酒废水处理性能。碳纤维用作阳极,带有生物膜的普通碳毡用作阴极。当水力停留时间(HRT)为 14.7 h 时,在长期稳定运行下,可实现相对较高的化学需氧量(COD)去除效率 91.7%-95.7%。MFC 在 300 Ω的外部电阻下显示出 0.434 V 的开路电压和 830 mW/m³的最大功率密度。为了评估 MFC 的电化学性能,进行了电化学测量,结果表明阳极的极化电阻是 MFC 的主要限制因素。由于实现了高 COD 去除效率,我们得出结论,本实验中用生物阴极构建的顺序式阳极-阴极 MFC 可为啤酒废水处理提供一种新方法。