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[香椿树化学成分的研究]

[Study on chemical constituents of tress of Toona ciliata].

作者信息

Li Jia-Zhou, Mo Hua-Nong, Ning Xian-Mao

机构信息

Yulin Normal University, Yulin 537000, China.

出版信息

Zhong Yao Cai. 2009 Oct;32(10):1539-42.

Abstract

OBJECTIVE

To study the chemical constituents of the tress of Toona ciliata.

METHODS

The compounds were isolated by many kinds of chromatography methods and identified on the basis of physico-chemical characters and spectroscopic analysis.

RESULTS

Seven compounds were obtained from the petrol and chloroform extracts of the tress of Toona ciliata, and their structures were identified as 3-Acetoxy-17-furan-3-yl-1-hydroxy-1, 4, 4, 10, 13-pentamethyl-12-oxo-tetradecahydro-16, 20-dioxa-cyclopropa [14, 15] cyclopenta [alpha] phenanthrene-7-carboxylic acid methyl ester (I), beta-sitosterol (II), stigmasterol (III), n-C35H72 (IV), palmitinic acid (V), n-C20H42 (VI), 3-(3-Propyl-[1,1',3',1"]tercyclohexan-3"-yl)-propan-1-ol (VII).

CONCLUSION

Compounds I, IV, VI, VII are isolated from this plant for the first time and compound I is a new compound.

摘要

目的

研究红椿树的化学成分。

方法

采用多种色谱方法分离化合物,并根据理化性质和光谱分析进行鉴定。

结果

从红椿树的石油醚和氯仿提取物中得到7个化合物,其结构分别鉴定为3-乙酰氧基-17-呋喃-3-基-1-羟基-1,4,4,10,13-五甲基-12-氧代-十四氢-16,20-二氧杂-环丙烷[14,15]环戊烷[α]菲-7-羧酸甲酯(Ⅰ)、β-谷甾醇(Ⅱ)、豆甾醇(Ⅲ)、正三十五烷(Ⅳ)、棕榈酸(Ⅴ)、正二十烷(Ⅵ)、3-(3-丙基-[1,1',3',1"]三环己烷-3"-基)-丙醇(Ⅶ)。

结论

化合物Ⅰ、Ⅳ、Ⅵ、Ⅶ为首次从该植物中分离得到,化合物Ⅰ为新化合物。

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