Li Jia-Zhou, Mo Hua-Nong, Ning Xian-Mao
Yulin Normal University, Yulin 537000, China.
Zhong Yao Cai. 2009 Oct;32(10):1539-42.
To study the chemical constituents of the tress of Toona ciliata.
The compounds were isolated by many kinds of chromatography methods and identified on the basis of physico-chemical characters and spectroscopic analysis.
Seven compounds were obtained from the petrol and chloroform extracts of the tress of Toona ciliata, and their structures were identified as 3-Acetoxy-17-furan-3-yl-1-hydroxy-1, 4, 4, 10, 13-pentamethyl-12-oxo-tetradecahydro-16, 20-dioxa-cyclopropa [14, 15] cyclopenta [alpha] phenanthrene-7-carboxylic acid methyl ester (I), beta-sitosterol (II), stigmasterol (III), n-C35H72 (IV), palmitinic acid (V), n-C20H42 (VI), 3-(3-Propyl-[1,1',3',1"]tercyclohexan-3"-yl)-propan-1-ol (VII).
Compounds I, IV, VI, VII are isolated from this plant for the first time and compound I is a new compound.
研究红椿树的化学成分。
采用多种色谱方法分离化合物,并根据理化性质和光谱分析进行鉴定。
从红椿树的石油醚和氯仿提取物中得到7个化合物,其结构分别鉴定为3-乙酰氧基-17-呋喃-3-基-1-羟基-1,4,4,10,13-五甲基-12-氧代-十四氢-16,20-二氧杂-环丙烷[14,15]环戊烷[α]菲-7-羧酸甲酯(Ⅰ)、β-谷甾醇(Ⅱ)、豆甾醇(Ⅲ)、正三十五烷(Ⅳ)、棕榈酸(Ⅴ)、正二十烷(Ⅵ)、3-(3-丙基-[1,1',3',1"]三环己烷-3"-基)-丙醇(Ⅶ)。
化合物Ⅰ、Ⅳ、Ⅵ、Ⅶ为首次从该植物中分离得到,化合物Ⅰ为新化合物。