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碳酸丙烯酯中氧化石墨的剥落和氧化石墨烯片的热还原。

Exfoliation of graphite oxide in propylene carbonate and thermal reduction of the resulting graphene oxide platelets.

机构信息

Department of Mechanical Engineering, The University of Texas, Austin, TX 78712, USA.

出版信息

ACS Nano. 2010 Feb 23;4(2):1227-33. doi: 10.1021/nn901689k.

Abstract

Graphite oxide was exfoliated and dispersed in propylene carbonate (PC) by bath sonication. Heating the graphene oxide suspensions at 150 degrees C significantly reduced the graphene oxide platelets; paper samples comprising such reduced graphene oxide platelets had an electrical conductivity of 5230 S/m. By adding tetraethylammonium tetrafluoroborate (TEA BF(4)) to the reduced graphene oxide/PC slurry and making a two-cell ultracapacitor, specific capacitance values of about 120 F/g were obtained.

摘要

氧化石墨通过浴式超声剥离并分散在碳酸丙烯酯(PC)中。将氧化石墨烯悬浮液加热至 150 摄氏度可显著减小氧化石墨烯片层的尺寸;由这种还原氧化石墨烯片层组成的纸张样品具有 5230 S/m 的电导率。通过向还原氧化石墨烯/PC 浆料中添加四乙铵四氟硼酸(TEA BF(4))并制作双电层超级电容器,可获得约 120 F/g 的比电容值。

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