Hirschfeld T
Appl Opt. 1974 Jun 1;13(6):1435-7. doi: 10.1364/AO.13.001435.
Sensitivity often restricts remote Raman spectrometers to operate at ranges inside their very large hyper-focal distances. Operation against a daylit background then requires minimizing the system etendue. This can be done by focusing the system at the range of interest; the depth of field is then etendue limited and varies with the square of the range. For the usual case of depth of field limited sampling depth, this cancels the inverse square range effect on signal strength, making the signal range independent (if atmospheric absorption is neglected). This concept is proven analytically and experimentally.
灵敏度常常限制远程拉曼光谱仪在其非常大的超焦距范围内运行。在日光背景下进行测量时,需要将系统的扩展量降至最低。这可以通过将系统聚焦在感兴趣的距离来实现;此时景深受扩展量限制,并随距离的平方而变化。对于景深限制采样深度的常见情况,这抵消了信号强度随距离平方反比的影响,使信号强度与距离无关(若忽略大气吸收)。这一概念已通过理论分析和实验得到验证。