-o-碳硼烷辅助增强三芳基硼的路易斯酸度。
o-Carborane-assisted Lewis acidity enhancement of triarylboranes.
机构信息
Department of Chemistry, KAIST, Daejeon 305-701, Republic of Korea.
出版信息
Chem Commun (Camb). 2010 Feb 21;46(7):1138-40. doi: 10.1039/b918263b. Epub 2009 Dec 15.
DOI:10.1039/b918263b
PMID:20126739
Abstract
The introduction of an o-carborane cage into the triarylborane significantly enhances the Lewis acidity of the boron atom leading to large increase in fluoride ion affinity.
摘要
在三芳基硼中引入 o-碳硼烷笼显著增强了硼原子的路易斯酸度，导致氟离子亲合力大幅增加。
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