Instrument Centre for Solid-State NMR Spectroscopy, Interdisciplinary Nanoscience Center (iNANO), Department of Chemistry, Aarhus University, DK-8000 Aarhus C, Denmark.
Chem Commun (Camb). 2010 Mar 28;46(12):2103-5. doi: 10.1039/b926699b. Epub 2010 Feb 9.
Precise values are reported for a quite large (95)Mo quadrupole coupling and an unusually large (95)Mo chemical shift anisotropy in MoS(2), values that have been retrieved by analysis of a well-resolved, highly complex 14.1 T (95)Mo MAS NMR spectrum displaying both the central and satellite transitions.
文中报道了在 MoS(2) 中相当大的 (95)Mo 四极耦合和不寻常大的 (95)Mo 化学位移各向异性的确切值,这些值是通过分析在 14.1 T (95)Mo MAS NMR 谱中解析度非常高、高度复杂的谱线,同时显示了中心和卫星跃迁,而得到的。