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由氧化胺表面活性剂形成的蠕虫状胶束的粘弹性溶液。

Viscoelastic solutions formed by worm-like micelles of amine oxide surfactant.

机构信息

CEMIN, Centro di Eccellenza Materiali Innovativi Nanostrutturati, Dipartimento di Chimica, Università di Perugia, Via Elce di Sotto 8, I-06123 Perugia, Italy.

出版信息

J Colloid Interface Sci. 2010 Jun 1;346(1):100-6. doi: 10.1016/j.jcis.2010.02.035. Epub 2010 Feb 19.

Abstract

Formation and properties of viscoelastic wormlike aqueous micellar solutions of the zwitterionic surfactant p-dodecyloxybenzyldimethylamine oxide (pDoAO) were studied. Semi-dilute aqueous solutions of pDoAO show a sharp increase in viscosity, which exceeds 160 cST for concentrations >50 mM, leading to viscoelastic solutions. Viscoelasticity relates to the surfactant charge type. In fact this viscoelastic system reverses to fluid when acid is added (pH<2), which changes the system to cationic. Under acidic conditions the system resembles solutions of the similar cationic surfactant p-dodecyloxybenzyltrimethylammonium bromide, (pDoTABr) in terms of viscosity. Properties of aqueous solutions of pDoAO were investigated by dynamic light scattering (DLS), rheology and small angle neutron scattering (SANS). Data support the idea that small micelles grow in length (wormlike or threadlike micelles) as surfactant concentration increases and viscoelastic solutions form as micelles become entangled. The micellar diameter as calculated by different techniques is about 5 nm.

摘要

两性离子表面活性剂 p-十二烷氧基苯甲基二甲胺氧化物(pDoAO)的粘弹性蠕虫状水胶束溶液的形成和性质。 pDoAO 的半稀水溶液的粘度急剧增加,当浓度>50mM 时,粘度超过 160cST,导致粘弹性溶液。粘弹性与表面活性剂电荷类型有关。事实上,当添加酸(pH<2)时,这种粘弹性体系会反转成流体,从而将体系转变为阳离子型。在酸性条件下,该体系在粘度方面类似于类似的阳离子表面活性剂 p-十二烷氧基苯甲基三甲基溴化铵(pDoTABr)的溶液。通过动态光散射(DLS)、流变学和小角中子散射(SANS)研究了 pDoAO 水溶液的性质。数据支持这样的观点,即随着表面活性剂浓度的增加,小胶束的长度增加(蠕虫状或线状胶束),并且当胶束缠结时形成粘弹性溶液。不同技术计算得到的胶束直径约为 5nm。

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