Centre for Intelligent Systems Research, Deakin University, Vic., Australia.
Electrophoresis. 2010 Apr;31(8):1366-75. doi: 10.1002/elps.200900717.
This study presents the dielectrophoretic (DEP) assembly of multi-walled carbon nanotubes (MWCNTs) between curved microelectrodes for the purpose of trapping polystyrene microparticles within a microfluidic system. Under normal conditions, polystyrene particles exhibit negative DEP behaviour and are repelled from microelectrodes. Interestingly, the addition of MWCNTs to the system alters this situation in two ways: first, they coat the surface of particles and change their dielectric properties to exhibit positive DEP behaviour; second, the assembled MWCNTs are highly conductive and after the deposition serve as extensions to the microelectrodes. They establish an array of nanoelectrodes that initiates from the edge of microelectrodes and grow along the electric field lines. These nanoelectrodes can effectively trap the MWCNT-coated particles, since they cover a large portion of the microchannel bottom surface and also create a much stronger electric field than the primary microelectrodes as confirmed by our numerical simulations. We will show that the presence of MWCNT significantly changes performance of the system, which is investigated by trapping sample polystyrene particles with plain, COOH and goat anti-mouse IgG surfaces.
本研究通过在弯曲微电极之间进行电泳(DEP)组装多壁碳纳米管(MWCNT),将聚苯乙烯微球捕获在微流控系统内。在正常条件下,聚苯乙烯颗粒表现出负 DEP 行为,会被微电极排斥。有趣的是,向系统中添加 MWCNT 会以两种方式改变这种情况:首先,它们覆盖在颗粒表面并改变其介电性质以表现出正 DEP 行为;其次,组装的 MWCNT 具有高导电性,并且在沉积后充当微电极的延伸。它们建立了一个纳米电极阵列,从微电极的边缘开始并沿着电场线生长。这些纳米电极可以有效地捕获涂覆 MWCNT 的颗粒,因为它们覆盖了微通道底部表面的很大一部分,并且如我们的数值模拟所证实的那样,还产生了比主微电极强得多的电场。我们将展示 MWCNT 的存在会显著改变系统的性能,这是通过捕获具有光滑、COOH 和山羊抗小鼠 IgG 表面的聚苯乙烯样品颗粒来研究的。