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用蓖麻外果皮制备的活性炭通过吸附从水溶液中去除孔雀石绿。

Removal of malachite green from aqueous solution by activated carbon prepared from the epicarp of Ricinus communis by adsorption.

机构信息

Department of Chemistry, Karpagam University, Coimbatore 641021, India.

出版信息

J Hazard Mater. 2010 Jul 15;179(1-3):178-86. doi: 10.1016/j.jhazmat.2010.02.076. Epub 2010 Mar 1.

Abstract

The use of low-cost, locally available, highly efficient and eco-friendly adsorbents has been investigated as an ideal alternative to the current expensive methods of removing dyes from wastewater. This study investigates the potential use of activated carbon prepared from the epicarp of Ricinus communis for the removal of malachite green (MG) dye from simulated wastewater. The effects of different system variables, adsorbent dosage, initial dye concentration, pH and contact time were investigated and optimal experimental conditions were ascertained. The results showed that as the amount of the adsorbent increased, the percentage of dye removal increased accordingly. Optimum pH value for dye adsorption was 7.0. Maximum dye was sequestered within 50 min of the start of every experiment. The adsorption of malachite green followed the pseudo-second-order rate equation and fits the Langmuir, Freundlich, Dubinin-Radushkevich (D-R) and Tempkin equations well. The maximum removal of MG was obtained at pH 7 as 99.04% for adsorbent dose of 1 g 50 mL(-1) and 25 mg L(-1) initial dye concentration at room temperature. Activated carbon developed from R. communis can be an attractive option for dye removal from diluted industrial effluents since test reaction made on simulated dyeing wastewater showed better removal percentage of MG.

摘要

本研究探讨了利用从蓖麻果皮制备的活性炭去除模拟废水中孔雀石绿(MG)染料的潜在用途。考察了不同体系变量、吸附剂用量、初始染料浓度、pH 值和接触时间对去除效果的影响,确定了最佳实验条件。结果表明,随着吸附剂用量的增加,染料去除率相应提高。吸附染料的最佳 pH 值为 7.0。在每个实验开始的 50 分钟内,最大量的染料被螯合。MG 的吸附符合准二级速率方程,并很好地符合朗缪尔、弗伦德利希、杜宾-拉什科夫斯基(D-R)和坦普金方程。在 pH 7、吸附剂用量为 1 g/50 mL 和初始染料浓度为 25 mg/L 的条件下,室温下对 MG 的最大去除率为 99.04%。从蓖麻开发的活性炭可以成为从稀释工业废水中去除染料的一种有吸引力的选择,因为对模拟染色废水进行的测试反应显示出了更好的 MG 去除率。

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