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空间限制控制着发生贝洛索夫-扎博廷斯基反应的聚合物凝胶中的自振荡。

Spatial confinement controls self-oscillations in polymer gels undergoing the Belousov-Zhabotinsky reaction.

作者信息

Kuksenok Olga, Yashin Victor V, Balazs Anna C

机构信息

Chemical Engineering Department, University of Pittsburgh, Pittsburgh, Pennsylvania 15261, USA.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2009 Nov;80(5 Pt 2):056208. doi: 10.1103/PhysRevE.80.056208. Epub 2009 Nov 23.

Abstract

Chemoresponsive gels undergoing the Belousov-Zhabotinsky (BZ) reaction exhibit self-sustained pulsations, which can be harnessed to perform mechanical work. In technological applications, the gels would typically be confined between hard surfaces and thus, it is essential to establish how confinement affects these distinctive oscillations. Using theory and simulation, we pinpoint regions in phase space where the dynamic behavior of BZ gels critically depends on the presence of confining walls. We then illustrate how the wave propagation within thin samples can be tailored by selectively introducing "cut outs" in the bounding surfaces. The oscillations in the latter films are localized in specified areas, so the system contains well-defined oscillatory and nonoscillatory regions. The cut outs provide an effective means of tuning the mechanical action within the film and provide a route for tailoring the functionality of the material.

摘要

经历贝洛索夫-扎博廷斯基(BZ)反应的化学响应凝胶会呈现出自持续脉动,这种脉动可被利用来执行机械功。在技术应用中,凝胶通常会被限制在坚硬表面之间,因此,确定限制条件如何影响这些独特的振荡至关重要。通过理论和模拟,我们在相空间中确定了区域,其中BZ凝胶的动态行为严重依赖于限制壁的存在。然后我们说明了如何通过在边界表面选择性地引入“切口”来调整薄样品内的波传播。后一种薄膜中的振荡局限于特定区域,因此系统包含明确界定的振荡和非振荡区域。这些切口提供了一种调节薄膜内机械作用的有效方法,并为定制材料的功能提供了一条途径。

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