Chahine Gilbert, Kityk Andriy V, Knorr Klaus, Lefort Ronan, Guendouz Mohammed, Morineau Denis, Huber Patrick
Institut de Physique de Rennes, UMR 6251, Université de Rennes 1, 35042 Rennes, France.
Phys Rev E Stat Nonlin Soft Matter Phys. 2010 Mar;81(3 Pt 1):031703. doi: 10.1103/PhysRevE.81.031703. Epub 2010 Mar 15.
We report combined optical birefringence and neutron scattering measurements on the liquid crystal 12CB nanoconfined in mesoporous silicon layers. This liquid crystal exhibits strong nematic-smectic coupling responsible for a discontinuous isotropic-to-smectic phase transition in the bulk state. Confined in porous silicon, 12CB is subjected to strong anisotropic quenched disorder: a short-ranged smectic state evolves out of a paranematic phase. This transformation appears continuous, losing its bulk first-order character. This contrasts with previously reported observations on liquid crystals under isotropic quenched disorder. In the low temperature phase, both orientational and translational order parameters obey the same power law.
我们报告了对介孔硅层中纳米受限的液晶12CB进行的光学双折射和中子散射联合测量。这种液晶表现出强烈的向列-近晶耦合,这导致了其在本体状态下从各向同性到近晶相的不连续相变。受限在多孔硅中时,12CB会受到强烈的各向异性淬火无序:一种短程近晶态从顺列相演化而来。这种转变似乎是连续的,失去了其本体的一级特征。这与之前报道的关于在各向同性淬火无序下液晶的观察结果形成对比。在低温相中,取向序参量和平移序参量都遵循相同的幂律。