National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan.
Anal Chem. 2010 May 1;82(9):3519-22. doi: 10.1021/ac9024126.
Both anatase and rutile are well-known as stable phases of TiO(2). In real-life samples, TiO(2) is most likely to be a mixture of those phases rather than pure anatase and rutile, and therefore quantitative analysis is extremely important. It is basically possible to determine the average ratio by X-ray diffraction (XRD) using differences in the crystal structure, but it is not easy to do so when attempting mapping by point-by-point scanning. The present paper describes the successful application of newly developed projection-type XRD imaging, which is an extremely rapid and highly efficient method.
锐钛矿和金红石都是 TiO(2) 的稳定相。在实际样品中,TiO(2) 很可能是这两种相的混合物,而不是纯锐钛矿和金红石,因此定量分析极其重要。基本可以通过 X 射线衍射 (XRD) 利用晶体结构的差异来确定平均比例,但逐点扫描进行映射时则不容易做到。本文介绍了新开发的投影式 XRD 成像的成功应用,这是一种极其快速和高效的方法。