杯[4]芳烃磺酸盐作为形成荧光噻唑橙 H-聚集物的模板。
Calix[4]arene sulfonate as a template for forming fluorescent thiazole orange H-aggregates.
机构信息
Chemistry Department, University of Calgary, 2500 University drive N.W., T2N 1N4, Calgary, Canada.
出版信息
Chem Commun (Camb). 2010 May 28;46(20):3595-7. doi: 10.1039/c002128h. Epub 2010 Apr 7.
DOI:10.1039/c002128h
PMID:20372742
Abstract
The unexpected interaction between thiazole orange (TO) and calix[4]arene sulfonate is reported herein. H-Aggregates of TO switching on their fluorescence in solution are observed. Surprisingly, fluorescence enhancement is not linked to host-guest inclusion, but rather to calix[4]arene sulfonate serving as a template for several TO molecules.
摘要
本文报道了噻唑橙（TO）与杯[4]芳烃磺酸盐之间意想不到的相互作用。在溶液中，TO 的 H-聚集物会打开其荧光。令人惊讶的是，荧光增强与主客体包合无关，而是与杯[4]芳烃磺酸盐作为多个 TO 分子的模板有关。
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