Centre for Research on the Ecological Impacts of Coastal Cities, Marine Ecology Laboratories, School of Biological Sciences, University of Sydney, NSW 2006, Australia.
Environ Sci Technol. 2010 May 1;44(9):3404-9. doi: 10.1021/es903784e.
The human population generates vast quantities of waste material. Macro (>1 mm) and microscopic (<1 mm) fragments of plastic debris represent a substantial contamination problem. Here, we test hypotheses about the influence of wind and depositional regime on spatial patterns of micro- and macro-plastic debris within the Tamar Estuary, UK. Debris was identified to the type of polymer using Fourier-transform infrared spectroscopy (FT-IR) and categorized according to density. In terms of abundance, microplastic accounted for 65% of debris recorded and mainly comprised polyvinylchloride, polyester, and polyamide. Generally, there were greater quantities of plastic at downwind sites. For macroplastic, there were clear patterns of distribution for less dense items, while for microplastic debris, clear patterns were for denser material. Small particles of sediment and plastic are both likely to settle slowly from the water-column and are likely to be transported by the flow of water and be deposited in areas where the movements of water are slower. There was, however, no relationship between the abundance of microplastic and the proportion of clay in sediments from the strandline. These results illustrate how FT-IR spectroscopy can be used to identify the different types of plastic and in this case was used to indicate spatial patterns, demonstrating habitats that are downwind acting as potential sinks for the accumulation of debris.
人类产生了大量的废物。塑料碎片的宏观(>1 毫米)和微观(<1 毫米)碎片是一个严重的污染问题。在这里,我们测试了关于风和沉积环境对英国塔玛河河口内微塑料和大塑料碎片空间分布模式影响的假设。使用傅里叶变换红外光谱(FT-IR)对碎片进行聚合物类型的识别,并根据密度进行分类。就丰度而言,记录的碎片中有 65%是微塑料,主要由聚氯乙烯、聚酯和聚酰胺组成。通常,下风处的塑料数量更多。对于大塑料,低密度物品的分布模式明显,而对于微塑料碎片,密度较大的材料则有明显的分布模式。小颗粒的沉积物和塑料都可能从水柱中缓慢沉降,并可能被水流携带,沉积在水流速度较慢的区域。然而,微塑料的丰度与滩线上沉积物中粘土的比例之间没有关系。这些结果说明了傅里叶变换红外光谱如何用于识别不同类型的塑料,在这种情况下,它被用于指示空间模式,表明下风的栖息地可能是碎片积累的潜在汇。