从关岛棕树蛇（Boiga irregularis）体表脂质中提取的新型酮二烯。

New ketodienes from the integumental lipids of the Guam brown tree snake, Boiga irregularis.

作者信息

Murata Y, Yeh H J, Pannell L K, Jones T H, Fales H M, Mason R T

机构信息

Laboratory of Bioorganic Chemistry, National Institute of Diabetes, Digestive and Kidney Diseases, Bethesda, Maryland 20892.

出版信息

J Nat Prod. 1991 Jan-Feb;54(1):233-40. doi: 10.1021/np50073a024.

DOI:10.1021/np50073a024

PMID:2045818

Abstract

A mixture of six new long chain ketodienes, (6Z,26Z)-pentatriacontadien-2-one [1], (8Z,26Z)-pentatriacontadien-2-one [2], (6Z,27Z)-hexatriacontadien-2-one [3], (8Z,27Z)-hexatriacontadien-2-one [4], (6Z,28Z)-heptatriacontadien-2-one [5], and (8Z,28Z)-heptatriacontadien-2-one [6], has been separated from the cuticular lipids of the Guam brown tree snake Boiga irregularis. Their structures were determined by chemical and spectral means.

摘要

从关岛棕树蛇（Boiga irregularis）的表皮脂质中分离出了六种新的长链酮二烯混合物，即(6Z,26Z)-三十五碳二烯-2-酮[1]、(8Z,26Z)-三十五碳二烯-2-酮[2]、(6Z,27Z)-三十六碳二烯-2-酮[3]、(8Z,27Z)-三十六碳二烯-2-酮[4]、(6Z,28Z)-三十七碳二烯-2-酮[5]和(8Z,28Z)-三十七碳二烯-2-酮[6]。它们的结构通过化学和光谱方法确定。