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评估铁纳米粒子树脂去除水中砷酸盐的性能。

Evaluating the performance of iron nanoparticle resin in removing arsenate from water.

机构信息

School of Public Health, Tehran University of Medical Sciences, Tehran, Iran.

出版信息

J Environ Sci Health A Tox Hazard Subst Environ Eng. 2010;45(8):946-50. doi: 10.1080/10934521003772337.

Abstract

This research was undertaken to evaluate the effectiveness of a hybrid sorbent resin (Lewatit FO36) with goethite structure for removing arsenate from water. Column experiments (with constant flow rate of 8 mL/min, corresponding to 2 min empty bed contact time (EBCT)) were conducted to evaluate the adsorption capacity of resin before and after regeneration and effects of chloride, sulfate, bicarbonate and combined competing ions for arsenate removal from water. The adsorption capacity was approximately 3.229 mg/g that was reduced to 2.826 mg/g after regeneration with 12.48% decrease, which indicates to a successful regeneration procedure. Chloride and sulfate ions had no significant effects on arsenate removal but arsenic removal decreased in the presence of bicarbonate and combined ions. This reduction may be due to the ability of bicarbonate ions in extracting and mobilizing the arsenate ions from iron oxyhydroxides. Results of this study showed that Lewatit FO36 could be developed as a suitable sorbent for arsenate removal.

摘要

本研究旨在评估具有针铁矿结构的混合吸附树脂(Lewatit FO36)去除水中砷酸盐的效果。通过柱实验(恒定流速为 8mL/min,相应的空床接触时间(EBCT)为 2min),评估了树脂在再生前后的吸附容量以及氯离子、硫酸根离子、碳酸氢根离子和混合竞争离子对水中砷酸盐去除的影响。树脂的吸附容量约为 3.229mg/g,再生后降至 2.826mg/g,下降了 12.48%,表明再生程序是成功的。氯离子和硫酸根离子对砷酸盐的去除没有显著影响,但碳酸氢根离子和混合离子的存在会降低砷的去除率。这种降低可能是由于碳酸氢根离子具有从铁氢氧化物中提取和迁移砷酸盐离子的能力。本研究结果表明,Lewatit FO36 可以开发为一种去除砷酸盐的合适吸附剂。

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