通过双脲两亲棒状胶束的自分类形成共存的疏水隔室。
Coexisting hydrophobic compartments through self-sorting in rod-like micelles of bisurea bolaamphiphiles.
机构信息
Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
出版信息
J Am Chem Soc. 2010 Jun 16;132(23):7842-3. doi: 10.1021/ja101872x.
Multiple, coexisting hydrophobic compartments have been created in water using molecular self-sorting among mixtures of bolaamphiphiles with differently spaced urea groups in their hydrophobic parts. The selective incorporation of bisurea functionalized fluorescent probes showed that different bolaamphiphiles form separate populations of rod-like micelles, which dynamically coexist in solution, each micelle binding to its correspondingly functionalized guests.
利用混合的具有不同间隔脲基的两亲性双子分子之间的分子自分类，在水中创建了多个共存的疏水性隔室。具有双脲基功能的荧光探针的选择性掺入表明，不同的两亲性双子形成了单独的棒状胶束群体，这些胶束在溶液中动态共存，每个胶束都与相应功能化的客体结合。
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