Di Vita A
DICAT, Universita' di Genova-1, via Montallegro, 16145 Genova, Italy.
Phys Rev E Stat Nonlin Soft Matter Phys. 2010 Apr;81(4 Pt 1):041137. doi: 10.1103/PhysRevE.81.041137. Epub 2010 Apr 29.
Ten necessary criteria for stability of various dissipative fluids and plasmas are derived from the first and the second principle of thermodynamics applied to a generic small mass element of the system, under the assumption that local thermodynamic equilibrium holds everywhere at all times. We investigate the stability of steady states of a mixture of different chemical species at the same temperature against volume-preserving perturbations. We neglect both electric and magnetic polarization, and assume negligible net mass sources and particle diffusion. We assume that both conduction- and radiation-induced heat losses increase with increasing temperature. We invoke no Onsager symmetry, no detailed model of heat transport and production, no "Extended Thermodynamics," no "Maxent" method, and no "new" universal criterion of stability for steady states of systems with dissipation. Each criterion takes the form of--or is a consequence of--a variational principle. We retrieve maximization of entropy for isolated systems at thermodynamic equilibrium, as expected. If the boundary conditions keep the relaxed state far from thermodynamic equilibrium, the stability criterion we retrieve depends also on the detailed balance of momentum of a small mass element. This balance may include the nablap-related force, the Lorenz force of electromagnetism and the forces which are gradients of potentials. In order to be stable, the solution of the steady-state equations of motion for a given problem should satisfy the relevant stability criterion. Retrieved criteria include (among others) Taylor's minimization of magnetic energy with the constraint of given magnetic helicity in relaxed, turbulent plasmas, Rayleigh's criterion of stability in thermoacoustics, Paltridge 's maximum entropy production principle for Earth's atmosphere, Chandrasekhar' minimization of the adverse temperature gradient in Bénard's convective cells, and Malkus' maximization of viscous power with the constraint of given mean velocity for turbulent shear flow in channels. It turns out that characterization of systems far from equilibrium, e.g., by maximum entropy production is not a general property but--just like minimum entropy production--is reserved to special systems. A taxonomy of stability criteria is derived, which clarifies what is to be minimized, what is to be maximized and with which constraint for each problem.
在始终处处保持局部热力学平衡的假设下,从应用于系统中一个普通小质量元的热力学第一和第二原理推导出各种耗散流体和等离子体稳定性的十个必要标准。我们研究了在相同温度下不同化学物种混合物稳态对体积保持扰动的稳定性。我们忽略电和磁极化,并假设净质量源和粒子扩散可忽略不计。我们假设传导和辐射引起的热损失都随温度升高而增加。我们不采用昂萨格对称性、不采用热传输和产生的详细模型、不采用“扩展热力学”、不采用“最大熵”方法,也不采用耗散系统稳态稳定性的“新”通用标准。每个标准都采用变分原理的形式,或者是变分原理的结果。正如预期的那样,我们得到了热力学平衡时孤立系统的熵最大化。如果边界条件使松弛态远离热力学平衡,我们得到的稳定性标准还取决于一个小质量元动量的详细平衡。这种平衡可能包括与nabla相关的力、电磁的洛伦兹力以及作为势梯度的力。为了稳定,给定问题的稳态运动方程的解应满足相关的稳定性标准。得到的标准包括(但不限于)泰勒在松弛的湍流等离子体中在给定磁螺旋度约束下使磁能最小化、热声学中瑞利稳定性标准、帕尔特里奇关于地球大气的最大熵产生原理、钱德拉塞卡在贝纳德对流元胞中使不利温度梯度最小化,以及马尔库斯在通道中湍流剪切流给定平均速度约束下使粘性功率最大化。结果表明,例如通过最大熵产生来表征远离平衡的系统不是一个普遍性质,而是——就像最小熵产生一样——仅适用于特殊系统。我们推导了稳定性标准的分类法,它阐明了每个问题要最小化、最大化的是什么以及有哪些约束条件。