基于六苯并苯的环形离域的二维分子布线。
2-Dimensional molecular wiring based on toroidal delocalization of hexaarylbenzene.
机构信息
Chemical Resources Laboratory, Tokyo Institute of Technology, R1-27, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan.
出版信息
Chem Commun (Camb). 2010 Jul 7;46(25):4529-31. doi: 10.1039/c0cc00128g. Epub 2010 May 18.
PMID:20485728
Abstract
A series of hexaarylbenzenes having two peripheral thienyliron substituents has been prepared, and it is revealed that the two metal centres communicate with each other through toroidal delocalization among the peripheral aromatic groups.
摘要
一系列具有两个外围噻吩基铁取代基的六芳基苯已被制备，结果表明两个金属中心通过外围芳基之间的环形离域相互作用。
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